Alloy Steel — Chrome-Moly & Low-Alloy Grades

Chromium-molybdenum and low-alloy steels for elevated-temperature pressure service, hard-wearing components and high-strength engineering parts.

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Alloy Steel — Material Overview

Alloy steel adds chromium, molybdenum, nickel and vanadium to carbon steel to raise creep strength at temperature, hardenability and toughness. The chromium-molybdenum ("chrome-moly") family — P1, P11, P12, P22, P5, P9, P91 and P92 — is the backbone of power-plant, refinery and boiler service, where it resists hydrogen attack and holds strength at temperatures carbon steel cannot.

The low-alloy AISI/SAE grades — 4130, 4140, 4340 and their EN equivalents — are through-hardening steels for shafts, gears, high-strength fasteners and machinery parts. ACERO ALLOYS supplies alloy steel pipes, fittings, flanges, plates, bars and fasteners to ASTM/ASME specifications with mill test certification.

11grades listed
7,850 kg/m³typical density
6product forms

Available Grades

The grades below are the ones most often asked for. Each grade stays on this page — the material-first way to browse.

A335 P1 / A182 F1

UNS K11522

½Mo carbon-molybdenum grade — the entry chrome-moly for moderate elevated-temperature steam and process piping where plain carbon steel runs out of creep strength.

A335 P11 / A182 F11

UNS K11597 EN / W.Nr. 1.7335

1¼Cr-½Mo grade for steam lines and process piping to about 540 °C — the entry grade of chrome-moly service.

A335 P12 / A182 F12

UNS K11562

1Cr-½Mo grade between P1 and P11 — the standard steam-superheater and process-piping steel for service around 500 – 550 °C.

A335 P22 / A182 F22

UNS K21590 EN / W.Nr. 1.7383

2¼Cr-1Mo grade — the classic refinery and power-plant grade for headers, steam piping and hydrogen service to about 600 °C.

A335 P5 / A182 F5

UNS K41545 EN / W.Nr. 1.7362

5Cr-½Mo grade with resistance to sulphidation and hydrogen corrosion — furnace tubes and refinery hot service.

A335 P9 / A182 F9

UNS K90901

9Cr-1Mo grade for higher-temperature furnace and boiler duty with good sulphidation resistance.

A335 P91 / A182 F91

UNS K91560 EN / W.Nr. 1.4903

Modified 9Cr-1Mo-VNb grade with martensitic microstructure — the modern grade for ultra-supercritical power-plant main steam lines to about 620 °C.

A335 P92 / A182 F92

UNS K92460

9Cr-2W-VNb martensitic grade with boron and nitrogen — higher creep strength than P91 for ultra-supercritical main steam and reheat lines to about 650 °C, with a smaller wall thickness than lower grades.

AISI 4130

UNS G41300 EN / W.Nr. 1.7218

½Cr-½Mo low-alloy steel with good weldability — structural tubing, pressure fittings and automotive/aerospace parts.

AISI 4140 / EN19

UNS G41400 EN / W.Nr. 1.7225

1Cr-½Mo medium-carbon steel with high hardenability — the standard grade for shafts, spindles, bolts and machinery components in the quenched-and-tempered condition.

AISI 4340 / EN24

UNS G43400 EN / W.Nr. 1.6582

Ni-Cr-Mo steel with very high hardenability and toughness in thick sections — heavy-duty shafts, gears and landing-gear-type components.

Available Product Forms

Alloy Steel is offered in the product forms below. Availability varies by grade and size — confirm the exact combination with our sales desk.

Pipes & Tubes

Pipes & Tubes

Seamless and welded pipes and tubes to ASTM/ASME, IS and BS specifications — including boiler, air-preheater and corten tubes.

Sheets, Plates & Coils

Sheets, Plates & Coils

Hot-rolled and cold-rolled sheets, plates, coils, circles and flats in standard and cut sizes.

Pipe Fittings

Pipe Fittings

Butt-weld, forged and socket-weld fittings — elbows, tees, reducers, caps, stub ends, olets and nipples.

Flanges

Flanges

Weld neck, slip-on, blind, lap joint, socket weld, threaded, spectacle, ring joint, orifice and deck flanges to ASME B16.5, 150# – 2500#.

Bars, Rods & Wires

Bars, Rods & Wires

Bright and black round bars, square and hex bars, flats and wires in stainless, duplex, alloy, carbon and nickel-alloy grades.

Fasteners

Fasteners

Bolts, nuts, studs, washers and threaded rods in alloy and stainless grades.

Chemical Composition & Mechanical Properties

Chemical composition: nominal ranges as published in the common product standards — indicative and for comparison only. Mechanical properties: typical minimum values for the common product forms in the annealed / solution-treated condition. Always purchase against the current ASTM/EN specification and the mill test certificate.

A335 P1 / A182 F1

Chemical composition, % by mass
ElementContent
Molybdenum (Mo)0.44 – 0.65
Carbon (C)0.10 – 0.20
Manganese (Mn)0.30 – 0.80
Silicon (Si)0.10 – 0.50
Phosphorus (P)≤ 0.025
Sulphur (S)≤ 0.025
Mechanical properties
PropertyValue
Tensile strength (min)380 MPa
Yield strength (min)205 MPa

A335 P11 / A182 F11

Chemical composition, % by mass
ElementContent
Chromium (Cr)1.00 – 1.50
Molybdenum (Mo)0.44 – 0.65
Carbon (C)0.05 – 0.15
Manganese (Mn)0.30 – 0.60
Mechanical properties
PropertyValue
Tensile strength (min)415 MPa
Yield strength (min)205 MPa

A335 P12 / A182 F12

Chemical composition, % by mass
ElementContent
Chromium (Cr)0.80 – 1.25
Molybdenum (Mo)0.44 – 0.65
Carbon (C)0.05 – 0.15
Manganese (Mn)0.30 – 0.61
Silicon (Si)≤ 0.50
Phosphorus (P)≤ 0.025
Sulphur (S)≤ 0.025
Mechanical properties
PropertyValue
Tensile strength (min)415 MPa
Yield strength (min)205 MPa

A335 P22 / A182 F22

Chemical composition, % by mass
ElementContent
Chromium (Cr)1.90 – 2.60
Molybdenum (Mo)0.87 – 1.13
Carbon (C)0.05 – 0.15
Manganese (Mn)0.30 – 0.60
Mechanical properties
PropertyValue
Tensile strength (min)415 MPa
Yield strength (min)205 MPa

A335 P5 / A182 F5

Chemical composition, % by mass
ElementContent
Chromium (Cr)4.00 – 6.00
Molybdenum (Mo)0.45 – 0.65
Carbon (C)≤ 0.15
Mechanical properties
PropertyValue
Tensile strength (min)415 MPa
Yield strength (min)205 MPa

A335 P9 / A182 F9

Chemical composition, % by mass
ElementContent
Chromium (Cr)8.00 – 10.00
Molybdenum (Mo)0.90 – 1.10
Carbon (C)≤ 0.15
Mechanical properties
PropertyValue
Tensile strength (min)415 MPa
Yield strength (min)205 MPa

A335 P91 / A182 F91

Chemical composition, % by mass
ElementContent
Chromium (Cr)8.00 – 9.50
Molybdenum (Mo)0.85 – 1.05
Vanadium (V)0.18 – 0.25
Niobium (Nb)0.06 – 0.10
Carbon (C)0.08 – 0.12
Mechanical properties
PropertyValue
Tensile strength (min)585 MPa
Yield strength (min)415 MPa

A335 P92 / A182 F92

Chemical composition, % by mass
ElementContent
Chromium (Cr)8.50 – 9.50
Molybdenum (Mo)0.30 – 0.60
Tungsten (W)1.50 – 2.00
Vanadium (V)0.15 – 0.25
Niobium (Nb)0.04 – 0.09
Nitrogen (N)0.03 – 0.07
Boron (B)0.001 – 0.006
Carbon (C)0.07 – 0.13
Manganese (Mn)0.30 – 0.60
Silicon (Si)≤ 0.50
Phosphorus (P)≤ 0.020
Sulphur (S)≤ 0.010
Mechanical properties
PropertyValue
Tensile strength (min)620 MPa
Yield strength (min)440 MPa

AISI 4130

Chemical composition, % by mass
ElementContent
Chromium (Cr)0.80 – 1.10
Molybdenum (Mo)0.15 – 0.25
Carbon (C)0.28 – 0.33
Manganese (Mn)0.40 – 0.60
Mechanical properties
PropertyValue
Tensile strength (Q&T, typical)670 – 900 MPa
Yield strength (Q&T, typical)435 – 700 MPa

AISI 4140 / EN19

Chemical composition, % by mass
ElementContent
Chromium (Cr)0.80 – 1.10
Molybdenum (Mo)0.15 – 0.25
Carbon (C)0.38 – 0.43
Manganese (Mn)0.75 – 1.00
Mechanical properties
PropertyValue
Tensile strength (Q&T, typical)850 – 1080 MPa
Yield strength (Q&T, typical)650 – 950 MPa

AISI 4340 / EN24

Chemical composition, % by mass
ElementContent
Nickel (Ni)1.65 – 2.00
Chromium (Cr)0.70 – 0.90
Molybdenum (Mo)0.20 – 0.30
Carbon (C)0.38 – 0.43
Mechanical properties
PropertyValue
Tensile strength (Q&T, typical)980 – 1180 MPa
Yield strength (Q&T, typical)780 – 1000 MPa

Physical Properties

Alloy Steel — physical properties
PropertyValue
Density7.85 g/cm³ (7850 kg/m³)
Thermal conductivity (P22, 100 °C)≈ 37 W/m·K
Modulus of elasticity≈ 200 – 210 GPa

Industrial Applications

  • Power-plant steam piping, headers and boiler tubes (P11–P91)
  • Refinery furnace tubes and hot hydrocarbon service
  • Hydrogen and sulphidation-corrosion service
  • High-strength shafts, gears and machinery parts (4140, 4340)
  • High-strength bolting and fasteners
  • Pressure-vessel and exchanger components

Applicable Standards

Standards commonly applied to Alloy Steel products
StandardScope
ASTM A335 / ASME SA335Seamless ferritic alloy-steel pipe for high-temperature service
ASTM A234 / ASME SA234Piping fittings of wrought carbon and alloy steel
ASTM A182 / ASME SA182Forged or rolled alloy-steel flanges, fittings and valves
ASTM A387 / ASME SA387Chromium-molybdenum pressure-vessel plates
ASTM A193 B7 / B7M / B16Alloy-steel bolting for high-temperature service
ASTM A320Alloy-steel bolting for low-temperature service
EN 10083Quenched and tempered steels (EN grades)

Quality & Documentation

Alloy steel is supplied against ASTM/ASME or EN specifications with EN 10204 Type 3.1 certification, heat-number traceability and, for chrome-moly grades, the applicable hardness and microstructure controls. NDE, impact testing and third-party inspection can be arranged with the enquiry.

Related Engineering Calculators

Frequently Asked Questions

What does the P-number in A335 grades mean?

The number series (P5, P9, P11, P22, P91) reflects the chromium-molybdenum balance: higher numbers generally mean higher alloy content and higher allowable service temperature — P11 (1¼Cr) to about 540 °C, P22 (2¼Cr) to about 600 °C and P91 (9Cr-VNb) to about 620 °C.

Why is P91 different from other chrome-moly grades?

P91 is a modified 9Cr-1Mo steel with controlled vanadium and niobium. Its martensitic structure and fine precipitates give roughly double the creep strength of P22, allowing thinner walls in ultra-supercritical power-plant piping. It requires careful welding and heat treatment.

What is the difference between AISI 4140 and 4340?

4340 adds about 1.65–2% nickel to the 4140-type Cr-Mo chemistry, giving deeper hardenability and higher toughness in thick sections. 4140 covers most general high-strength parts; 4340 is chosen for heavy-duty shafts and critical components.

What bolting suits alloy-steel flanges?

ASTM A193 Gr. B7 studs with A194 Gr. 2H nuts are the standard pairing for F11/F22 flanges — the recommended combination is shown by our flange calculator.

Can you supply A387 plates in normalized-and-tempered condition?

Plate is normally supplied in the normalized-and-tempered or quenched-and-tempered condition required by the specification. Confirm the wall thickness, class and heat-treatment condition with the enquiry.

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